7719-12-2

  • English Name: Phosphorus Trichloride
  • CAS Number: 7719-12-2
  • Molecular Formula: PCl₃
  • Molecular Weight: 137.33 g/mol

Physical Properties

  • Appearance: Colorless to pale yellow fuming liquid with a pungent odor.
  • Melting Point: -112°C.
  • Boiling Point: 75.5°C.
  • Density: 1.574 g/mL at 25°C.
  • Solubility: Soluble in benzene, carbon disulfide, ether, chloroform, and other halogenated organic solvents.
  • Refractive Index: n20/D 1.5148.

Chemical Properties

  • Stability: Stable but decomposes in moist air to form phosphoric acid and hydrochloric acid.
  • Reactivity:
    • Reacts violently with water, producing heat and toxic fumes.
    • Reacts with alcohols, amines, and other organic compounds.
    • Forms phosphorus pentachloride (PCl₅) when exposed to excess chlorine.

Uses

  • Organic Synthesis: Used as a chlorinating agent for alcohols, amines, and carboxylic acids.
  • Pesticides: Key raw material for manufacturing organophosphorus pesticides like malathion and parathion.
  • Pharmaceuticals: Used in the synthesis of drugs like sulfadiazine.
  • Dyes and Textiles: Used as a reagent in dye synthesis and textile finishing.
  • Other Applications: Used in the production of flame retardants, gasoline additives, and as a catalyst.

Safety Information

  • Toxicity: Highly toxic; inhalation, ingestion, and skin contact can cause severe health effects.
  • Health Hazards: Causes severe irritation to skin, eyes, and mucous membranes.
  • First Aid:
    • Skin Contact: Rinse with plenty of water.
    • Eye Contact: Rinse with water for at least 15 minutes.
    • Ingestion: Drink water and seek medical attention.
  • Storage: Store in a cool, dry place, away from moisture and strong oxidizers.

Environmental Information

  • Ecotoxicity: Very toxic to aquatic life.
  • Decomposition Products: Phosphoric acid, hydrochloric acid.

Transport Information

  • UN Number: 1809.
  • Hazard Class: 8 (Corrosive substances).

Packing and shipping