Перхлорат калия (KClO₄)7778-74-7

7778-74-7

  • Молекулярная формула: KClO₄

    Молекулярная масса: 138,55 г/моль

    Номер CAS: 7778-74-7

    Номер EINECS: 231-897-8

Физические свойства

  • Appearance: White crystalline solid or colorless crystals.
  • Density: 2.52 g/cm³.
  • Melting Point: 610°C (decomposes at 400°C).
  • Solubility:
    • Slightly soluble in cold water (0.75 g/100 mL at 0°C).
    • Soluble in boiling water (21.8 g/100 mL at 100°C).
    • Practically insoluble in alcohol.

Химические свойства

  • Oxidizing Agent: Potassium perchlorate is a strong oxidizer and can transfer oxygen to combustible materials, greatly increasing their rate of combustion.
  • Stability: Decomposes at temperatures above 400°C and may explode upon impact or when mixed with organic materials.
  • Reactivity: Reacts violently with reducing agents, such as metal powders (e.g., aluminum, magnesium) and sulfur.

Применение

  • Pyrotechnics and Explosives: Used in fireworks, explosive primers, ammunition percussion caps, and rocket propellants.
  • Medical Use: Used as an antithyroid agent to treat hyperthyroidism.
  • Analytical Chemistry: Used as an oxidizer in chemical syntheses and as a reagent in analytical chemistry.

Safety and Hazards

  • Health Hazards: Inhalation, ingestion, or contact with skin or eyes can cause severe irritation, burns, or death.
  • Fire and Explosion Risk: Potassium perchlorate can accelerate burning and may explode when heated or contaminated with organic materials.
  • Storage and Handling: Store in a cool, dry place away from combustible materials and reducing agents. Use protective equipment when handling.

Приготовление

  • Industrial Production: Prepared by treating an aqueous solution of sodium perchlorate with potassium chloride, exploiting the low solubility of KClO₄.
  • Alternative Methods: Can also be produced by neutralizing perchloric acid with potassium hydroxide.

Environmental Considerations

  • Ecotoxicity: Limited data available, but it is considered harmful to aquatic life.
  • Disposal: Dispose of in accordance with local regulations to avoid environmental contamination.

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